Thanks to its versatility, nitrile ruber, a.k.a. NBR and Buna-N, is one of the most widely used gasket materials. In this blog we’ll take a look at the attributes that make it the first choice in many gasket applications. We’ll also discuss when not to use it, and we’ll identify some more costly alternatives.
Nitrile Chemistry
Nitrile is a synthetic rubber with properties similar to those of natural rubber. It’s produced by polymerizing clear liquid acrylonitrile, used in the manufacture of various acrylic products, with butadiene. The resulting polymer forms long chains of carbon and hydrogen atoms. These become entangled and provide the elastic properties sought in most gasket materials.
Important Properties of Nitrile for Gasket Material
Nitrile is fairly soft and strong, with good elongation and low compression set, and is known for being abrasion-resistant. Specific numbers depend on the exact formulation and grade but are around:
- Durometer: 60
- Tensile strength: 1,000psi
- Elongation: 350%
- Working temperature range: -30 to +200 °F (-34 to +93 °C)
Nitrile has good resistance to most oils and fuels but is attacked by solvents like acetone and MEK, by the esters used in many fragrances and flavorings, and by aromatic hydrocarbons like benzene.
Nitrile is produced in an FDA grade for food industry applications. This is usually referred to as “white nitrile”.
Nitrile Limitations
In addition to a narrow temperature range and limited chemical resistance, nitrile has some other restrictions on its use. In particular, being susceptible to attack by ozone and UV light, it’s not a good choice for outdoor applications.
Nitrile rubber swells when exposed to oils. The extent, as defined in ASTM D2000, is from 10% to 60%, depending on the proportion of acrylonitride in the formulation.
Alternatives to Nitrile
For a wider temperature range or increased chemical resistance, two other gasket materials to consider are EPDM and FKM or Viton®. EPDM provides a moderate improvement but is a little more expensive. FKM has significantly better performance but is also considerably more expensive.
Our experts can help you determine whether nitrile is the best material for your application. Contact us to ask.